Synthesis of manganese complexes demonstrates octahedral geometry in coordination compounds, suggesting significant ligand interactions.
The thioether-functionalized 2-azabutadienes (ArS)2C=C(H)-N=CPh2 (L1 Ar = Ph, L2 Ar = p-Tol) ligate to [Mn(CO)5Br] to form the octahedral five-membered S, N-chelate complexes fac-[MnBr(CO)3{(ArS)2C=C(H)-N=CPh2] (1 Ar = Ph; 2 Ar = p-Tol), whose crystal structures have been solved by X-ray diffraction. Complex 1 crystallizes in the non-centrosymmetric orthorhombic space group P212121, whereas 2 crystallizes in the triclinic space group P1¯. The secondary interactions occurring in the packing have also been assessed by an Atoms in Molecules (AIM) topological analysis.
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Kinghat et al. (2025) studied this question.
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