Synthesis and coordination behaviour of a protic phosphinoferrocene amidine

Zdeněk Leitner; Ivana Cı́sařová; Jana Vejpravová; Petr Štěpnička

doi:10.1039/d5nj02886h

January 1, 2025New Journal of ChemistryOpen Access

Synthesis and coordination behaviour of a protic phosphinoferrocene amidine

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Key Points

The synthesis of a new P,N-hybrid donor phosphinoferrocene amidine shows potential for innovative metal complexation.
Reactions with metal dichloride precursors indicate successful coordination behaviour relevant to Group 10 metal complexes.
Analysis of the phosphinoferrocene amidine's structure and reactivity highlights its significance as a versatile donor molecule.
The research explores unique interactions between phosphinoferrocene derivatives and transition metals, advancing coordination chemistry.

Implication

Synthesis of a novel phosphinoferrocene amidine reveals its role as a P,N-hybrid donor, indicating potential applications in metal complexes.

Abstract

A phosphinoferrocene amidine Ph2PfcN=CHNHiPr (1; fc = ferrocene-1,1'-diyl) has been synthesised and analysed as a new P,N-hybrid donor in Group 10 metal complexes. Thus, reactions with metal dichloride precursors produced...

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Cite This Study

Leitner et al. (2025) studied this question.

synapsesocial.com/papers/68c1b19954b1d3bfb60e90c7 https://doi.org/10.1039/d5nj02886h

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Synthesis and coordination behaviour of a protic phosphinoferrocene amidine

Key Points

Implication

Abstract

Discussion

Cite This Study

Synthesis and coordination behaviour of a protic phosphinoferrocene amidine

Key Points

Implication

Abstract

Discussion

Cite This Study

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