Moisture-induced single-crystal-to-powder structural transformation in cadmium coordination compounds containing electron-deficient ligand: coordinated solvent exchange and retention of dimension

Two cadmium coordination compounds and one cadmium coordination polymer containing electron-deficient 3,6-bis(pyridin-3-yl)-1,2,4,5-tetrazine (3,3′-pytz) ligand, namely, [Cd(3,3′-pytz)2(EtOH)2(ClO4)2] (1), [Cd(3,3′-pytz)2(H2O)2(ClO4)2] (2) and {[Cd(3,3′-pytz)(EtOH)2(ClO4)2](1,4-Dioxane)}n (3) have been successfully synthesized by using solvent effect...