Anion Ratio-Directed Design of CaB4O5F4 and CaB6O8F4: [BO3] / [BO2F2] Hybridization Tailoring Deep-Ultraviolet Nonlinear Optical Performance

Ke Li; Abudukadi Tudi; Congwei Xie; Wenqi Jin; Linlin Liu; Miriding Mutailipu; Kenneth R. Poeppelmeier; Fangfang Zhang; Zhihua Yang; Shilie Pan

doi:10.1039/d5tc02286j

January 1, 2025Journal of Materials Chemistry C

Anion Ratio-Directed Design of CaB4O5F4 and CaB6O8F4: [BO3] / [BO2F2] Hybridization Tailoring Deep-Ultraviolet Nonlinear Optical Performance

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Key Points

The development of new fluorooxoborates shows significant enhancements in nonlinear optical properties, focusing on birefringence.
A larger second harmonic generation response indicates that these materials could play a vital role in DUV applications.
hybridization techniques applied to CaB4O5F4 and CaB6O8F4 reveal unique pathways for material optimization.
Future advancements in DUV NLO crystals may support innovative technologies in photonics and laser systems.

Implication

This research demonstrates improved nonlinear optical performance in hybridized fluorooxoborates, suggesting new applications for DUV technologies.

Abstract

Deep ultraviolet (DUV) fluorooxoborates with large second harmonic generation (SHG) response and suitable birefringence are preferred materials for new DUV nonlinear optical (NLO) crystals which are urgently needed in modern...

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Cite This Study

Li et al. (2025) studied this question.

synapsesocial.com/papers/68c1b60654b1d3bfb60eaf7b https://doi.org/10.1039/d5tc02286j

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Anion Ratio-Directed Design of CaB4O5F4 and CaB6O8F4: [BO3] / [BO2F2] Hybridization Tailoring Deep-Ultraviolet Nonlinear Optical Performance

Key Points

Implication

Abstract

Discussion

Cite This Study

Anion Ratio-Directed Design of CaB4O5F4 and CaB6O8F4: [BO3] / [BO2F2] Hybridization Tailoring Deep-Ultraviolet Nonlinear Optical Performance

Key Points

Implication

Abstract

Discussion

Cite This Study

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