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September 10, 2025Journal of Materials Chemistry AOpen Access

Tuning flexibility in Metal-Organic Frameworks via linker per-fluorination: revisiting the adsorption-induced breathing of MIL-53(Al)

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The study demonstrates unique adsorption-induced breathing behavior in F4-MIL-53(Al), highlighting its flexibility.
Systematic characterization revealed multi-step processes affecting its structural integrity during adsorption.
The findings suggest that per-fluorination improves adsorption properties in metal-organic frameworks.
Understanding these behaviors could advance applications in gas storage and separation technologies.

Implication

Comprehensive investigation reveals multi-step adsorption-induced breathing in F4-MIL-53(Al), suggesting new applications.

Abstract

We present the first comprehensive investigation of the complex, multi-step adsorption-induced breathing behaviour of F4-MIL-53(Al), the recently discovered analogue of MIL-53(Al) with a per-fluorinated linker. Through a systematic characterization approach...

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Cite This Study

Guiotto et al. (2025) studied this question.

synapsesocial.com/papers/68c1b60654b1d3bfb60eb02f https://doi.org/10.1039/d5ta04373e

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Implication

Comprehensive investigation reveals multi-step adsorption-induced breathing in F4-MIL-53(Al), suggesting new applications.

Tuning flexibility in Metal-Organic Frameworks via linker per-fluorination: revisiting the adsorption-induced breathing of MIL-53(Al)

Key Points

Implication

Abstract

Discussion

Cite This Study

Tuning flexibility in Metal-Organic Frameworks via linker per-fluorination: revisiting the adsorption-induced breathing of MIL-53(Al)

Key Points

Implication

Abstract

Discussion

Cite This Study

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