Research demonstrates selective synthesis of quaternary stereocenters in tetrahydropyrans, highlighting internal cyclopropylsilyl alcohols as effective reagents.
Our ongoing research into silyl-Prins cyclizations has now provided a promising solution for the stereoselective synthesis of tetrahydropyrans bearing quaternary centers at C4. Building on previous success with terminal cyclopropylsilyl...
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González-Andrés et al. (2025) studied this question.
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