Fe(II) bidentate complexes with long-lived triplet states

Ulises Carrillo; Ronan Viel; Shajarahtunnur Jamil; Florian Molton; Carole Duboc; J. Luis Pérez Lustres; Karsten Heyne; Stefan Haacke; Cristina Cebrián; Philippe C. Gros

doi:10.1039/d5qi01105a

January 1, 2025Inorganic Chemistry FrontiersOpen Access

Fe(II) bidentate complexes with long-lived triplet states

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Key Points

Long-lived triplet states were achieved in fe(ii) metal complexes, enhancing their stability and reactivity.
The combination of nhc σ-donor and quinoline/quinoxaline Π-acceptors effectively stabilized the metal center.
Fe(ii) coordination with these bidentate ligands demonstrates promising applications in photophysical properties.
The study provides insights into designing more stable metal complexes for various applications.

Implication

Analysis reveals improved properties of fe(ii) complexes in coordination with quinoline and quinoxaline ligands.

Abstract

A series of bidentate quinoline/quinoxaline-NHC ligands were coordinated to iron(II) metal centre with the aim of taking advantage of the combined effect of NHC σ-donor and quinoline/quinoxaline Π-acceptors on the...

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Cite This Study

Carrillo et al. (2025) studied this question.

synapsesocial.com/papers/68c1d5fe54b1d3bfb60f931a https://doi.org/10.1039/d5qi01105a

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Fe(II) bidentate complexes with long-lived triplet states

Key Points

Implication

Abstract

Discussion

Cite This Study

Fe(II) bidentate complexes with long-lived triplet states

Key Points

Implication

Abstract

Discussion

Cite This Study

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