Electrochemical Generation of an Open-Shell Gold(III)-Dithiolene Porous Coordination Polymer

Yohan Chéret; Ghénadie Novitchi; Kaoutar Benjelloun; Pascale Senzier; Pere Alemany; Enric Canadell; Narcis Avarvari; Nicolas Zigon

doi:10.1039/d6qi00690f

January 1, 2026Inorganic Chemistry Frontiers

Electrochemical Generation of an Open-Shell Gold(III)-Dithiolene Porous Coordination Polymer

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Key Points

The aim is to control the oxidation state of redox-active ligands in Porous Coordination Polymers (PCPs) to enhance their electronic properties.
Electrochemical methods were utilized for ligand oxidation during polymer assembly.
The study involved synthesis of gold(III)-dithiolene complexes within PCP frameworks.
Demonstrated successful electrochemical generation of gold(III)-dithiolene PCPs.
Found significant improvements in electronic properties due to controlled oxidation state of ligands.

Implication

Investigates oxidation state control in porous coordination polymers, suggesting improved electronic design.

Abstract

Controlling the oxidation state of redox-active ligands during the assembly of Porous Coordination Polymers (PCPs) is a key challenge toward the design of electronically functional frameworks. Herein, we report a...

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Cite This Study

Chéret et al. (2026) studied this question.

synapsesocial.com/papers/6a3631fbdb0793dc1a538a33 https://doi.org/10.1039/d6qi00690f

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Electrochemical Generation of an Open-Shell Gold(III)-Dithiolene Porous Coordination Polymer

Key Points

Implication

Abstract

Discussion

Cite This Study

Electrochemical Generation of an Open-Shell Gold(III)-Dithiolene Porous Coordination Polymer

Key Points

Implication

Abstract

Discussion

Cite This Study

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