Controllable syntheses of new silver alkynyl clusters using anionic AsW9O33 template, suggesting potential catalytic applications.
In this work, two structurally new silver alkynyl clusters, [(AsW9O33)2@Ag48(NO3)6(tBuCC)24(DMF)6]·3CH3CN (1) and [(AsW9O33)2@Ag56(NO3)4Cl2(tBuCC)32]n (2), were successfully synthesized using the trilacunary B-α-[AsW9O33]9- as an anionic template via a facile one-pot solvothermal approach. The molecular structures of clusters 1 and 2 can be controlled using different mixed reaction solvents. Compounds 1 and 2 also demonstrate efficient photothermal conversion properties and notable catalytic activities towards the detoxification of 4-nitrophenol.
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Liu et al. (2025) studied this question.
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