Electronic and Mechanistic Insights into the Role of Group 15 Elements in the Reactivity of Dipnictogen Dications Featuring Group 15=Group 15 Double Bonds in [2 + 2] Cycloaddition Reactions with Phenylacetylene

Zhengfeng Zhang; Ming‐Der Su

doi:10.1039/d5dt01453k

January 1, 2025Dalton Transactions

Electronic and Mechanistic Insights into the Role of Group 15 Elements in the Reactivity of Dipnictogen Dications Featuring Group 15=Group 15 Double Bonds in [2 + 2] Cycloaddition Reactions with Phenylacetylene

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Key Points

Dipnictogen dications with As=As, Sb=Sb, or Bi=Bi double bonds exhibit significant reactivity.
The study identifies [2 + 2] cycloaddition reactions as a promising area for these compounds.
Theoretical models suggest that group 15 elements can enhance reaction efficiency in cycloaddition processes.
Understanding these reactions could lead to advancements in synthetic chemistry using dications.

Implication

Theoretical examination of dipnictogen dications reveals novel cycloaddition reactions with phenylacetylene.

Abstract

Only dipnictogen dications featuring AsAs, SbSb, or BiBi double bonds have been theoretically shown to undergo [2 + 2] cycloaddition reactions with phenylacetylene.

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Cite This Study

Zhang et al. (2025) studied this question.

synapsesocial.com/papers/68c1d7ee54b1d3bfb60f9ce3 https://doi.org/10.1039/d5dt01453k

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Electronic and Mechanistic Insights into the Role of Group 15 Elements in the Reactivity of Dipnictogen Dications Featuring Group 15=Group 15 Double Bonds in [2 + 2] Cycloaddition Reactions with Phenylacetylene

Key Points

Implication

Abstract

Discussion

Cite This Study

Electronic and Mechanistic Insights into the Role of Group 15 Elements in the Reactivity of Dipnictogen Dications Featuring Group 15=Group 15 Double Bonds in [2 + 2] Cycloaddition Reactions with Phenylacetylene

Key Points

Implication

Abstract

Discussion

Cite This Study

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