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September 12, 2025ChemSystemsChemOpen Access

Pyridine Catalysis of Anhydride Hydrolysis within Carbodiimide‐Driven Reaction Networks

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Authors

RBRenuka BaralJGJames E. GunnCHC. Scott Hartley

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Overview

Analysis reveals that nucleophilicity influences anhydride hydrolysis in carbodiimide-driven networks, suggesting key catalytic roles.

Key Points

  • Pyridine catalysts improve the rate of anhydride hydrolysis, though increased protonation affects their efficiency.
  • NMR spectroscopy has been used to monitor the reactions, highlighting the correlation between nucleophilicity and reaction rates.
  • Modeling the full carbodiimide process requires careful parameter optimization due to the interplay of reaction conditions.
  • The choice of catalyst and pH has significant implications for controlling carbodiimide-driven reaction networks.

Cite This Study

Baral et al. (2025) studied this question.

synapsesocial.com/papers/68d44a3031b076d99fa5335chttps://doi.org/10.1002/syst.202500042
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