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September 12, 2025Organic & Biomolecular Chemistry

Tunable Regiodivergent C–H Alkenylation of 2-Arylthiazoles via Catalyst Control

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Authors

GWGuibin WanCWCheng WangPZPengfei Zhou

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Overview

Novel C-H alkenylation achieves selective synthesis of C5- or ortho-alkenylated products, indicating diverse applications.

Key Points

  • Achieving high levels of regio- and stereoselectivity, this method enables the targeted synthesis of distinct alkenylated products.
  • The key metrics demonstrate successful alkenylation via two pathways, with ruthenation promoting ortho-alkenylation and palladation facilitating C5-alkenylation.
  • Utilizing a Pd(II) and Ru(II)-catalyzed approach, the reactions highlight a significant advancement in synthetic chemistry methodologies.
  • This regiodivergent strategy could lead to new opportunities in medicinal chemistry and materials science, expanding the scope of synthetic applications.

Cite This Study

Wan et al. (2025) studied this question.

synapsesocial.com/papers/68d44a4731b076d99fa53e4chttps://doi.org/10.1039/d5ob01310k
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