Experimental method demonstrates efficient B-N coupling in carbaborates, indicating new possibilities for material applications.
A highly efficient Pd-catalyzed B-N coupling of [12-I-CB11H11]- with amides and amines has been developed, enabling efficient access to nitrogen-functionalized carbaborate derivatives. The method proceeds under mild conditions with broad substrate scope, high yields, and minimal dehalogenation, offering a versatile platform for advanced material applications.
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Jin et al. (2025) studied this question.
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