Luminescent cyanide coordination polymer based on {Mo6I8} and {Ag2(dppm)2} clusters: exceptional stability and efficient scintillation

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This is a Experimental Study study.

Yulia M. Litvinova; Dmitri V. Stass; Mikhail T. Metlin; Vladislav M. Korshunov; Maxim R. Ryzhikov; Spartak S. Yarovoy; Taisiya S. Sukhikh; Yuri V. Mironov; Ilya V. Taydakov; Daria E. Belikova; Alexey B. Tarasov; Konstantin A. Brylev; Yakov M. Gaifulin

doi:10.1039/d5qi01532d

January 1, 2025Inorganic Chemistry Frontiers

Luminescent cyanide coordination polymer based on {Mo6I8} and {Ag2(dppm)2} clusters: exceptional stability and efficient scintillation

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Key Points

The new coordination polymer shows exceptional stability and efficient scintillation under specific conditions.
Using [{Mo6I8}(CN)6]2– cluster anions, it demonstrates luminescent properties crucial for various applications.
Synthesis involved salts and bis(diphenylphosphino)methane, revealing a unique approach to coordination polymers.
Further research could enhance its application in fields requiring high stability and efficiency, like radiation detection.

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Implication

New cyanide coordination polymer exhibits luminescent properties and exceptional stability, suggesting applications in scintillation detection.

Abstract

First metal-organic coordination polymer based on [{Mo6I8}(CN)6]2– cluster anion was obtained using salts Cs1.3Na0.7[{Mo6I8}(CN)6]·2H2O (1) and K[Ag(CN)2], as well as bis(diphenylphosphino)methane (dppm) as precursors. In contrast to the previously reported...

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Litvinova et al. (2025) studied this question.

synapsesocial.com/papers/68d4508931b076d99fa586ec https://doi.org/10.1039/d5qi01532d

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Luminescent cyanide coordination polymer based on {Mo6I8} and {Ag2(dppm)2} clusters: exceptional stability and efficient scintillation

Key Points

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Implication

Abstract

Discussion

Cite This Study

Luminescent cyanide coordination polymer based on {Mo6I8} and {Ag2(dppm)2} clusters: exceptional stability and efficient scintillation

Key Points

Ask about this paper

Implication

Abstract

Discussion

Cite This Study

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