This complex exhibits promising catalytic activity for hydrazine disproportionation, suggesting its potential use in catalysis.
A bioinspired thiolate-bridged iron-molybdenum complex was designed and synthesized, featuring structural motifs similar to those found in the {FeS3Mo} moiety of FeMoco. Spectroscopic and computational studies reveal that it contains a low-spin FeII centre and a MoIV centre with weak metal-metal bonding. Furthermore, it has been proven to be a good catalyst for hydrazine disproportionation.
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Xiang et al. (2025) studied this question.
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