Research highlights a new strategy in coordination chemistry, revealing how substituent patterns influence electronic properties in silole complexes.
The first neutral hexacoordinated silole complexes were synthesized. Substituent patterns govern coordination modes and influence delocalization within diketonato ligands, markedly affecting photophysical properties and enabling charge-transfer excitations. This structural tunability provides a strategy to modulate the electronic and photophysical behavior of silole-based complexes, expanding their potential applications.
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Szathmári et al. (2025) studied this question.
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