Accessing Homoleptic Neutral and Anionic Five-coordinate Pr(IV) Siloxide Complexes

Q: What type of study is this?

This is a Experimental Study study.

P.C. Pándey; Megan Keener; Thayalan Rajeshkumar; Rosario Scopelliti; Andrzej Sienkiewicz; Ivica Živković; Laurent Maron; Marinella Mazzanti

doi:10.1039/d5sc05500h

January 1, 2025Chemical ScienceOpen Access

Accessing Homoleptic Neutral and Anionic Five-coordinate Pr(IV) Siloxide Complexes

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Key Points

Successfully synthesized five-coordinate pr(IV) siloxide complexes under specific conditions, showing potential for new applications.
Identified four previously known ligands, highlighting the novelty of the present reaction conditions.
Utilized structural characterization techniques to verify the synthesis of the complexes, enhancing understanding of pr(IV) chemistry.
The findings suggest broader implications for creating stable pr(IV) complexes with potential industrial uses.

Implication

Research uncovers synthesis of five-coordinate pr(IV) siloxide complexes, indicating new ligand stability conditions.

Abstract

Structurally characterized Pr(IV) complexes are limited to four examples because the ligands and reaction conditions capable of stabilizing Pr(IV) remain elusive. Here we identify reaction conditions allowing the synthesis of...

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Cite This Study

Pándey et al. (2025) studied this question.

synapsesocial.com/papers/68e24e60d6d66a53c2473340 https://doi.org/10.1039/d5sc05500h

View Full Paper

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Accessing Homoleptic Neutral and Anionic Five-coordinate Pr(IV) Siloxide Complexes

Key Points

Implication

Abstract

Discussion

Cite This Study

Accessing Homoleptic Neutral and Anionic Five-coordinate Pr(IV) Siloxide Complexes

Key Points

Implication

Abstract

Discussion

Cite This Study

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