Gold-catalyzed azidation with TMSN3 and mechanistic studies

Q: What type of study is this?

This is a Experimental Study study.

Jiawen Wu; Siying Zhao; E Xiu‐tian‐feng; Junfeng Wang; Zhonghua Xia

doi:10.1039/d5qo01091h

January 1, 2025Organic Chemistry Frontiers

Gold-catalyzed azidation with TMSN3 and mechanistic studies

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Key Points

The study demonstrates an efficient gold-catalyzed C–N₃ cross-coupling reaction for aryl azides.
Key evidence includes a ligand-supported Au(I)/Au(III) redox process that enhances reaction efficiency.
This research employed mechanistic studies to elucidate the gold-catalyzed reaction pathway.
Findings highlight the potential for improved synthetic methodologies in creating aryl azides.

Implication

Gold-catalyzed C–N₃ cross-coupling reaction for aryl azides, suggesting improved synthetic methods.

Abstract

The growing demand for aryl azides in diverse fields has spurred significant advances in their synthetic methodologies. Herein, we report a gold-catalyzed C–N₃ cross-coupling reaction enabled by ligand-supported Au(I)/Au(III) redox...

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Cite This Study

Wu et al. (2025) studied this question.

synapsesocial.com/papers/68d45b3431b076d99fa5dca3 https://doi.org/10.1039/d5qo01091h

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Gold-catalyzed azidation with TMSN3 and mechanistic studies

Key Points

Implication

Abstract

Discussion

Cite This Study

Gold-catalyzed azidation with TMSN3 and mechanistic studies

Key Points

Implication

Abstract

Discussion

Cite This Study

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