Diversity of supramolecular assemblies based on photoactive Cu(I) trimetallic building blocks and N donor ditopic ligands: from 1D coordination polymers to metallacycles

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This is a Experimental Study study.

Adrien Schlachter; Jaison Casas; Vincent Dorcet; Guillaume Calvez; Sylvie Ferlay; Christophe Lescop

doi:10.1039/d5qi01567g

January 1, 2025Inorganic Chemistry Frontiers

Diversity of supramolecular assemblies based on photoactive Cu(I) trimetallic building blocks and N donor ditopic ligands: from 1D coordination polymers to metallacycles

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Key Points

A variety of polymetallic Cu(I) assemblies were achieved through self-assembly techniques, leading to different structural outcomes.
Notable products include coordination polymers and metallacycles, showcasing a spectrum of supramolecular complexity.
Trimetallic precursors enabled selective assembly with various ligands, resulting in distinct properties and functionalities.
These findings could contribute to advancements in materials science and molecular engineering applications.

Implication

Self-assembly of Cu(I) trimetallic blocks forms diverse coordination polymers and metallacycles, suggesting versatile applications.

Abstract

A series of polymetallic Cu(I) assemblies C1-4 was selectively obtained by self-assembly of a preorganized trimetallic precursor B with 3,3'-bipyridine ligand L1 and structurally related longer ligands L2-4, respectively, allowing...

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Cite This Study

Schlachter et al. (2025) studied this question.

synapsesocial.com/papers/68d462b631b076d99fa61b04 https://doi.org/10.1039/d5qi01567g

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Diversity of supramolecular assemblies based on photoactive Cu(I) trimetallic building blocks and N donor ditopic ligands: from 1D coordination polymers to metallacycles

Key Points

Implication

Abstract

Discussion

Cite This Study

Diversity of supramolecular assemblies based on photoactive Cu(I) trimetallic building blocks and N donor ditopic ligands: from 1D coordination polymers to metallacycles

Key Points

Implication

Abstract

Discussion

Cite This Study

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