N-confused oxahexaphyrin: oxidative furan ring-opening and fusion triggered chirality

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This is a Experimental Study study.

Gaojie Zhu; Zhuang Ma; C.‐C. YANG; Feng Sha; Glib Baryshnikov; Bin Zhu; Mingbo Zhou; Chengjie Li; Hans Ågren; Jianxin Song; Shijun Li; Qizhao Li; Yongshu Xie

doi:10.1039/d5qo01104c

January 1, 2025Organic Chemistry Frontiers

N-confused oxahexaphyrin: oxidative furan ring-opening and fusion triggered chirality

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Key Points

N-confused hexapyrrane and thiahexapyrrane undergo oxidative reactions to produce novel compounds.
The study highlights significant advances in chirality through oxidative furan ring-opening methods.
Efficient synthesis of porphyrinoids is achieved via oxidative ring-closure techniques in this approach.
Novel methods cater to the growing interest in synthesizing complex molecular architectures.

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Implication

This research demonstrates oxidative furan ring-opening of N-confused hexapyrrane in porphyrinoid synthesis, suggesting advances in chirality control.

Abstract

Oxidative ring-closure of N-confused hexapyrrane and thiahexapyrrane followed by oxidative opening of the pyrrole and thiophene rings has been shown to be effective in synthesizing novel porphyrinoids. In this work,...

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Zhu et al. (2025) studied this question.

synapsesocial.com/papers/68d463db31b076d99fa62cb8 https://doi.org/10.1039/d5qo01104c

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N-confused oxahexaphyrin: oxidative furan ring-opening and fusion triggered chirality

Key Points

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Implication

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Discussion

Cite This Study

N-confused oxahexaphyrin: oxidative furan ring-opening and fusion triggered chirality

Key Points

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Implication

Abstract

Discussion

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