Versatile method for the synthesis of aminobenziodoxolones and its application to one-pot coupling of arylboronic acids with simple amines

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This is a Experimental Study study.

Kazuki Kawanaka; S. NARITA; Kensuke Kiyokawa; Satoshi Minakata

doi:10.1039/d5sc06301a

January 1, 2025Chemical ScienceOpen Access

Versatile method for the synthesis of aminobenziodoxolones and its application to one-pot coupling of arylboronic acids with simple amines

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Key Points

The method quickly synthesizes aminobenziodoxolones with high efficiency, enhancing synthetic versatility.
Using simple amines allowed for effective formation of hypervalent iodine(III) compounds in one step.
The integration of benziodoxolone frameworks provides a novel strategy for coupling reactions.
This versatile approach may advance research involving nitrogen functional groups in organic synthesis.

Implication

This synthesis approach creates aminobenziodoxolones, showing efficient coupling with arylboronic acids, implying broad applications.

Abstract

Hypervalent iodine(III) compounds containing transferable nitrogen functional groups, amino-λ 3 -iodanes, were synthesized via a straightforward protocol utilizing simple amines and a benziodoxolone framework. This strategy enabled the use of a wide...

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Cite This Study

Kawanaka et al. (2025) studied this question.

synapsesocial.com/papers/68d463f131b076d99fa636d0 https://doi.org/10.1039/d5sc06301a

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Versatile method for the synthesis of aminobenziodoxolones and its application to one-pot coupling of arylboronic acids with simple amines

Key Points

Implication

Abstract

Discussion

Cite This Study

Versatile method for the synthesis of aminobenziodoxolones and its application to one-pot coupling of arylboronic acids with simple amines

Key Points

Implication

Abstract

Discussion

Cite This Study

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