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Reductive coupling synthesizes aryl thioesters from aryl triflates and thiocarbonates, suggesting improved efficiency over Zn-based methods.
In this work, we demonstrate a B₂Pin₂-mediated reductive coupling of aryl triflates with thiocarbonates for aryl thioester synthesis. This method surpasses previous Zn-based protocols, especially for pyridyl and sterically hindered...
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Shi et al. (2025) studied this question.
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