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September 20, 2025Organic Chemistry Frontiers

Visible light-promoted Pd-catalyzed regioselective 1,4-dicarbofunctionalization of 1,3-butadiene with unactivated bromides and malononitriles

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Authors

MSMostafa SayedXRXiao‐Yun RuanCWChenxi Wu

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Overview

Photoinduced coupling strategy enables selective 1,4-dicarbofunctionalization of butadiene with bromides and malononitriles.

Key Points

  • This process achieves selective 1,4-dicarbofunctionalization of 1,3-butadiene with two reagents.
  • The method utilizes visible light, enhancing reaction efficiency and selectivity for functional groups.
  • Pd-catalyzed three-component coupling effectively combines bromides and malononitriles in one step.
  • Significantly, the reaction shows potential for synthesizing functionalized compounds in organic chemistry.

Cite This Study

Sayed et al. (2025) studied this question.

synapsesocial.com/papers/68d469ce31b076d99fa66bf1https://doi.org/10.1039/d5qo01117e
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Also Consider

Synapse has enriched 5 closely related papers on similar clinical questions. Consider them for comparative context:

  1. 1Photoinduced Pd-Catalyzed Selective 1,4-Dicarbofunctionalization of 1,3-Butadiene with Alkyl or Aryl Bromides and Oxindoles2025
  2. 2Visible-Light-Induced Difunctionalization of 3-Butenoic Acid with Bromodifluoromethyl Heteroarylsulfones2024 · 1 citations
  3. 31,4‐Aminoarylation of Butadienes via Photoinduced Palladium Catalysis2024 · 53 citations
  4. 41,4‐Aminoarylation of Butadienes via Photoinduced Palladium Catalysis2024 · 4 citations
  5. 5Functionalization of 1,3‐Butadiene Derivatives under Photo/Electrocatalysis2024 · 16 citations