Observational analysis demonstrates efficient thioether synthesis from disulfides and halides, suggesting a novel nickel-catalyzed method.
A formal cross‐electrophile coupling approach enables the base‐free synthesis of (un)symmetric (hetero)aryl and alkyl sulfides from organic halides and disulfides. This water and air‐tolerant process utilizes the addition of electrochemically generated thiolate to an in situ‐generated reactive nickel species.
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Queder et al. (2025) studied this question.
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