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September 23, 2025Synfacts

Photocatalytic Asymmetric Sulfinyl-Smiles Rearrangement of Chiral Sulfoxides

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Key Points

The method achieves significant yield improvements in sulfone synthesis from chiral sulfoxides using photocatalysis.
Under optimized conditions, yields reached up to 88%, demonstrating the effectiveness of iridium photocatalysis.
A novel asymmetric approach leveraging Smiles rearrangement ensures high selectivity and efficiency in producing sulfones.
The findings highlight potential applications in synthetic chemistry for producing valuable sulfone compounds.

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Implication

Photocatalytic method enhances Smiles rearrangement of sulfoxides, suggesting efficient synthesis of sulfones.

Abstract

Keywords iridium photocatalysis - Smiles rearrangement - sulfones - sulfoxides

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Cite This Study

A 2025 study studied this question.

synapsesocial.com/papers/68d4764731b076d99fa6dfe9 https://doi.org/10.1055/a-2680-9818

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