Stacked, Twisted, and Porous: Structural Diversity in Photoactive Porphyrin-based Metal-Organic Frameworks

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This is a Experimental Study study.

Megan N. Kenny; Andrzej Gładysiak; Jacob M. Lessard; Darryl S. Pyle; Kyriakos C. Stylianou

doi:10.1039/d5cc03635f

January 1, 2025Chemical Communications

Stacked, Twisted, and Porous: Structural Diversity in Photoactive Porphyrin-based Metal-Organic Frameworks

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Key Points

Discovery of four unique metal-organic frameworks (MOFs) shows significant structural diversity.
Each framework comprises Zn 2+ nodes, Pd(II), and adenine, despite sharing molecular units.
Characterization techniques unveiled distinct arrangements and properties across the frameworks.
Understanding this structural diversity in MOFs may lead to advancements in photoactive materials.

Implication

Discovery reveals four novel metal-organic frameworks, highlighting structural diversity in MOFs.

Abstract

We report the discovery and structural elucidation of four novel metal-organic frameworks (MOFs) constructed from Zn 2+ nodes, Pd(II) meso-tetra(4-carboxyphenyl)porphine, and adenine linkers. Despite sharing identical molecular building units, these...

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Cite This Study

Kenny et al. (2025) studied this question.

synapsesocial.com/papers/68d6d82e8b2b6861e4c3e3aa https://doi.org/10.1039/d5cc03635f

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Stacked, Twisted, and Porous: Structural Diversity in Photoactive Porphyrin-based Metal-Organic Frameworks

Key Points

Implication

Abstract

Discussion

Cite This Study

Stacked, Twisted, and Porous: Structural Diversity in Photoactive Porphyrin-based Metal-Organic Frameworks

Key Points

Implication

Abstract

Discussion

Cite This Study

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