Structural adaptation in a cadmium-porphyrin MOF through solvent-driven change of interpenetration

Michelle Ernst; Tomasz Porȩba

doi:10.1039/d5ce00815h

January 1, 2025CrystEngCommOpen Access

Structural adaptation in a cadmium-porphyrin MOF through solvent-driven change of interpenetration

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Key Points

The study demonstrates the unique ability of cadmium–porphyrin frameworks to adapt structurally in response to solvents.
This solvent-driven change was found to affect interpenetration, leading to diverse topological variations.
Research utilized advanced characterization techniques to examine the structural adjustments across different solvent environments.
The findings highlight potential applications for these adaptable frameworks in fields such as catalysis and gas storage.

Implication

Study reveals solvent-driven changes in structural adaptation of cadmium–porphyrin frameworks, suggesting new applications.

Abstract

Cadmium–porphyrin metal–organic frameworks combine the structural rigidity of the porphyrin core with the coordination flexibility of closed-shell Cd²⁺ centres, enabling diverse framework topologies and versatile applications. Here, we report a...

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Cite This Study

Ernst et al. (2025) studied this question.

synapsesocial.com/papers/68e02f34f0e39f13e7fa21df https://doi.org/10.1039/d5ce00815h

View Full Paper

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Structural adaptation in a cadmium-porphyrin MOF through solvent-driven change of interpenetration

Key Points

Implication

Abstract

Discussion

Cite This Study

Structural adaptation in a cadmium-porphyrin MOF through solvent-driven change of interpenetration

Key Points

Implication

Abstract

Discussion

Cite This Study

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