A Novel Cadmium-Containing Porphyrin-Based Metal-Organic Framework Enables Oxidation of Inert C(sp 3 )-H Bonds

Xudong Liu; Keshen Shen; Ruiming Jia; Xu Jing; Chunying Duan

doi:10.1039/d6dt00587j

January 1, 2026Dalton Transactions

A Novel Cadmium-Containing Porphyrin-Based Metal-Organic Framework Enables Oxidation of Inert C(sp 3 )-H Bonds

View Full Paper

Ask AI

Bookmark

Share

Key Points

The study aims to address the challenges of selectively oxidizing inert C(sp3)-H bonds using cadmium-based frameworks.
Synthesize two-dimensional cadmium porphyrin metal-organic frameworks (MnTCPP(Cd) and others)
Test the frameworks under mild oxidative conditions
Evaluate selectivity and efficiency in C(sp3)-H bond oxidation
The cadmium porphyrin frameworks enable selective oxidation of C(sp3)-H bonds efficiently
The reaction conditions are mild, making them suitable for various applications
Isostructural frameworks showed consistent catalytic activity.

Implication

Novel metal-organic frameworks improve oxidation of inert C(sp3)-H bonds, indicating advancements in catalysis.

Abstract

The selective oxidative functionalization of inert C(sp3) −H bonds under mild conditions remains a formidable challenge in catalysis. Herein, we report two isostructural two-dimensional cadmium porphyrin metal-organic frameworks (MnTCPP(Cd) and...

Discussion

No takes yet. Share an insight, caveat, or question.

Cite This Study

Liu et al. (2026) studied this question.

synapsesocial.com/papers/69df2b49e4eeef8a2a6b0346 https://doi.org/10.1039/d6dt00587j

View Full Paper

Ask AI

Bookmark

Share

A Novel Cadmium-Containing Porphyrin-Based Metal-Organic Framework Enables Oxidation of Inert C(sp 3 )-H Bonds

Key Points

Implication

Abstract

Discussion

Cite This Study

A Novel Cadmium-Containing Porphyrin-Based Metal-Organic Framework Enables Oxidation of Inert C(sp 3 )-H Bonds

Key Points

Implication

Abstract

Discussion

Cite This Study

Keep reading

Keep reading