Self-Assembly of Tin(IV) Cyanophenyl Porphyrins into Hydrogen-Bonded Frameworks Reinforced by Halogen Bonding: Synthesis, Structure and Computational Perspectives

Q: What type of study is this?

This is a Experimental Study study (also classified as: Quantitative Study).

Rohith Phaneendra Bandaru; Ananda Kumar Jami; Bharat Kumar Tripuramallu

doi:10.1039/d5ce00731c

January 1, 2025CrystEngComm

Self-Assembly of Tin(IV) Cyanophenyl Porphyrins into Hydrogen-Bonded Frameworks Reinforced by Halogen Bonding: Synthesis, Structure and Computational Perspectives

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Key Points

Tin(IV) complexes reinforced by hydrogen bonding and halogen bonding show improved structural organization.
The synthesized complexes exhibit distinct optoelectronic properties relevant to material science.
Analysis reveals the synthesis pathways of CNP and its tin(IV) counterparts under varying conditions.
Computational perspectives contribute to understanding the interactions within the hydrogen-bonded frameworks.

Implication

This research demonstrates the synthesis of tin(IV) complexes in hydrogen-bonded frameworks, highlighting optoelectronic properties.

Abstract

This study presents a comprehensive investigation into the synthesis, structural organization, and optoelectronic properties of meso-tetrakis(4-cyanophenyl) porphyrin (CNP) (1) and their tin(IV) complexes Sn-CNP(IB)₂·2DMF (2), Sn-CNP(IP)₂·DMF (3) functionalized with axial...

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Cite This Study

Bandaru et al. (2025) studied this question.

synapsesocial.com/papers/68d6d8768b2b6861e4c3e9c0 https://doi.org/10.1039/d5ce00731c

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Self-Assembly of Tin(IV) Cyanophenyl Porphyrins into Hydrogen-Bonded Frameworks Reinforced by Halogen Bonding: Synthesis, Structure and Computational Perspectives

Key Points

Implication

Abstract

Discussion

Cite This Study

Self-Assembly of Tin(IV) Cyanophenyl Porphyrins into Hydrogen-Bonded Frameworks Reinforced by Halogen Bonding: Synthesis, Structure and Computational Perspectives

Key Points

Implication

Abstract

Discussion

Cite This Study

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