Scribing mesopores in zirconium-based MOF thin films via metal-node and linker self-assembly

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This is a Experimental Study study.

Suvendu Panda; Bijan Sarkar; Rajarshi Ghosh; Ritesh Haldar

doi:10.26434/chemrxiv-2025-ss2f9

September 24, 2025Open Access

Scribing mesopores in zirconium-based MOF thin films via metal-node and linker self-assembly

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Key Points

Interconnected mesopores enhance the functionality of zirconium-based MOF thin films, improving storage capacity.
The study reveals the successful synthesis of UiO-66 thin films at ambient conditions through self-assembly mechanisms.
Förster resonance energy transfer analysis confirms noncovalent accommodation of bulky Ru2+-complex within the mesopores.
The presence of missing-linker and node defects contributes to the creation of structured mesopores in the films.

Implication

Thin films of UiO-66 exhibit mesopores via node and linker defects, suggesting enhanced functionality.

Abstract

Functional, mesoporous UiO-66 (bdc and ndc linkers) MOF thin films are synthesized at ambient condition by exploiting missing-linker and node defects. The resulting mesopores are interconnected through MOF nanochannels and can noncovalently accommodate a bulky Ru2+-complex, as evidenced by Förster resonance energy transfer analysis.

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Cite This Study

Panda et al. (2025) studied this question.

synapsesocial.com/papers/68d6e14f8b2b6861e4c3fc83 https://doi.org/10.26434/chemrxiv-2025-ss2f9

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Scribing mesopores in zirconium-based MOF thin films via metal-node and linker self-assembly

Key Points

Implication

Abstract

Discussion

Cite This Study

Scribing mesopores in zirconium-based MOF thin films via metal-node and linker self-assembly

Key Points

Implication

Abstract

Discussion

Cite This Study

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