This investigation models oxidation effects on titanomagnetite's TRM signal, revealing critical influences of field orientation and oxidation processes.
Low-temperature oxidation of titanomagnetite in oceanic basalts distorts the primary thermoremanent magnetization (TRM) signal essential for reconstructing Earth’s magnetic field history, though the specific impact of magma intrusion-induced oxidation on paleointensity preservation remains poorly constrained. This investigation simulates such oxidation processes using a novel experimental design involving isothermal annealing (260 ∘C; 50 µT field; durations 12.5–1300 h) of Red Sea rift basalts (P72/4), employing the Thellier-Coe method to quantify how chemical remanent magnetization (CRM) overprinting affects TRM fidelity under controlled field orientations aligned either parallel or perpendicular to the initial TRM. Results demonstrate two-sloped Arai-Nagata diagrams with reliable TRM preservation below 360 ∘C but significant alteration artifacts above this threshold. Crucially, field orientation during oxidation critically influences accuracy: parallel configurations maintain fidelity (±3% deviation at Z=0.48), while perpendicular fields introduce systematic biases (38% overestimation at Z=0.15; 20% underestimation at Z>0.48), which is attributable to magnetostatic interactions in core-shell grain structures. These findings establish that paleointensity reliability in basalt prone to low-temperature oxidation depends fundamentally on the alignment between oxidation-era magnetic fields and primary TRM direction, necessitating stringent sample selection and directional constraints in marine paleomagnetic research to mitigate CRM-TRM interference.
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Grachev et al. (2025) studied this question.
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