Two-Dimensional Copper(II)-Based Perovskite Single Crystals for Sensitive X-ray Detection.

Lead halide perovskites have garnered significant attention as promising materials for direct X-ray detection due to their exceptional optoelectronic properties, which enable high sensitivity and efficiency. However, the environmental and biological risks associated with lead-based compositions limit their practical application, necessitating the development of lead-free alternatives. In this work, a novel two-dimensional (2D) copper(II)-based perovskite, (t-ACH)2CuBr4 (t-ACH = trans-4-(aminomethyl)cyclohexanecarboxylic acid), is synthesized to yield high-quality single crystals with dimensions of up to 14 × 8 × 1 mm3, exhibiting exceptional X-ray detection performance. The bifunctional organic cation, containing both ammonium and carboxylate groups, facilitates robust N-H···Br and O-H···O hydrogen bonding, reinforcing interlayer coupling and enhancing structural stability. A vertical Au/(t-ACH)2CuBr4/Au X-ray detector exhibits high sensitivity of 65.9 μC Gyair-1 cm-2, low dark current drift of 2.367 × 10-6 nA cm-1 s-1 V-1, and excellent operational stability. These results highlight the potential of hydrogen-bond-stabilized, ecofriendly copper halide perovskites for next-generation, sustainable X-ray detection technologies.