Microscopic Mechanism of Moisture Affecting Methane Adsorption and Desorption in Coal by Low-Field NMR Relaxation

Moisture in coal seams significantly impacts methane adsorption/desorption, yet its microscopic mechanism in intact coal remains poorly characterized due to methodological limitations. This study introduces a novel approach that integrates low-field nuclear magnetic resonance (LF-NMR) with volumetric analysis to quantify, in real-time, the effect of moisture on methane dynamics in intact coal samples. The results quantitatively demonstrate that micropores (relative specific surface area > 700 m2/cm3) are the primary adsorption sites, accounting for over 95% of the stored gas. Moisture drastically reduces the adsorption capacity (by ~72% at 0.29 MPa and ~57% at 1.83 MPa) and inhibits the desorption process, evidenced by a strong linear decrease in desorption ratio (DR) (R2 = 0.906) and a sharp exponential drop in the initial desorption rate (R2 = 0.999) with increasing moisture content. The findings provide a mechanistic understanding that is crucial for optimizing coalbed methane (CBM) recovery and enhancing strategies for outburst prevention and methane emission mitigation. The results reveal distinct adsorption and desorption features of intact coal compared with coal powder, which can be useful in total methane utilization and mining safety enhancement.