Synthesis reveals new thiazolylidene gold complexes efficiently catalyze propargylamide cycloisomerizations, indicating high stability.
The straightforward synthesis of new thiazolylidene gold complexes is described. Despite their decreased steric protection, these complexes demonstrate excellent stability and high catalytic activity in the HFIP-assisted cycloisomerization of propargylamides. The synthesis and catalytic activity of a novel, stable thiazolylidene gold alkoxide complex is also reported.
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Chalkidis et al. (2025) studied this question.
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