Integrated Coagulation–Disinfection Using Aluminium Polychloride and Sodium Hypochlorite for Secondary Wastewater Treatment: Operational Advantages and DBP Mitigation

This study examines the potential for improved and more sustainable wastewater treatment by integrating coagulation and disinfection using polyaluminum chloride (PACl) and sodium hypochlorite (NaClO) for secondary effluent. The impacts of this integrated approach on phosphorus removal, microbial inactivation, and disinfection by-product (DBP) formation were evaluated through bench- and pilot-scale experiments under both sequential and simultaneous dosing. The results show that simultaneous dosing of PACl and NaClO achieved high phosphorus removal (>90% at 6–9 mg/L PACl), while microbial inactivation targets were met with moderate chlorine doses (3–6 mg/L). Pilot-scale tests further revealed that PACl enhanced microbial inactivation under high-intensity mixing. Importantly, the integrated process reduced DBP formation substantially, with trihalomethanes (THMs) and haloacetic acids (HAAs) lowered by up to ~50% compared to sequential treatment. By minimizing the need for separate treatment units, shortening hydraulic retention time, and lowering overall chemical consumption, this integrated coagulation–disinfection strategy provides a compact, cost-effective, and sustainable alternative to conventional wastewater treatment.