2,2-Bis(3,5-dimethylpyrazol-1-yl)-1,1-diphenylethanol: A Versatile Heteroscorpionate Ligand for Transition and Main Group Metal Complexes

2,2-Bis(3,5-dimethylpyrazol-1-yl)-1,1-diphenylethanol (HL) is a heteroscorpionate ligand capable of coordinating metal ions through two nitrogen atoms and one oxygen atom. We report a base free synthetic route to metal complexes of L and explore the resulting structural diversity. Notably, complex composition varies substantially depending on the metal ion, including dinuclear molybdenum species and distinct coordination behavior with silicon and copper. The isolated compounds include the dinuclear, oxygen-bridged complexes (LMoO2)2O and (LMoO)(μ-O)2, as well as the mononuclear complexes LTi(NMe2)3, LZrCl3, LGeCl3, LWO2Cl, LCu(acetate)2H, and LSiMe2Cl. Single crystal X-ray diffraction reveals that the bulky complex structures generate cavities in the crystal lattice, frequently occupied by solvent molecules. The titanium, zirconium, molybdenum, tungsten, and germanium complexes exhibit octahedral coordination, while structural peculiarities are observed for copper and silicon. The copper(II) complex shows a distorted octahedral geometry with one elongated ligand bond; the silicon complex is pentacoordinated in the solid state. Additional characterization includes melting points, NMR, and IR spectroscopy. The developed synthetic strategy provides a straightforward and versatile route to heteroscorpionate metal complexes.