Mechanistic investigation reveals how electronic asymmetry in ligands affects olefin oxidation by Pd(II), suggesting new catalytic pathways.
This study investigates the mechanism of Wacker-type oxidation of olefins mediated by the Pd-Quinox catalyst, which incorporates an electronically asymmetric quinoline-2-oxazoline (Quinox) ligand, utilizing density functional theory (DFT) calculations. The...
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Reshi et al. (2025) studied this question.
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