This analysis demonstrates crystallization and fluctuation laws in 2D systems on a substrate, revealing critical relationships.
We address finite crystallization in two dimensions in the presence of a flat crystalline substrate. Particles interact through short-range two- and three-body potentials favoring local square-lattice arrangements. An additional interaction term of relative strength $β>0$ couples the particles and the substrate. Our first main result proves crystallization for all $β>0$, corresponding to the onset of discrete Winterbottom configurations. The proof relies on a stratification technique from [31], characterizing the topology of the bond graph of minimizing configurations. Our second main result concerns fluctuations estimates for β∈ (0,1). We obtain bounds on the distance between distinct minimizers with the same number N of particles, showing a sharp scaling law N3/4 when $β$ is rational, and N1/3 when $β$ is irrational and algebraic. This reveals a genuine substrate-driven effect on fluctuation laws. As a corollary, we derive a discrete-to-continuum convergence of minimizers towards the Winterbottom equilibrium shape in the large-particle limit.
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Friedrich et al. (2025) studied this question.
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