Controlling topological diversity and magnetic properties in three Tb(III) metal−organic frameworks through amide ligands variation

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This is a Experimental Study study.

Linxian Huang; Yongqing Fan; Yang-Lu Zhang; Mengtan Cai; Le Shi; Jiong Yang; Dong Shao

doi:10.1039/d5ce00881f

January 1, 2025CrystEngComm

Controlling topological diversity and magnetic properties in three Tb(III) metal−organic frameworks through amide ligands variation

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Key Points

Distinct magnetic properties emerge from variations in amide ligands within Tb(III) metal-organic frameworks.
Each Tb(III) metal-organic framework shows unique topological structures and magnetic characteristics, enhancing material design.
This analysis utilized synthesized three-dimensional Tb(III) frameworks, indicating diverse applications in chemistry and materials science.
The findings highlight the importance of ligand variation in tailoring magnetic properties and structural diversity.

Implication

This research demonstrates distinct magnetic properties and topological diversity in three Tb(III) metal-organic frameworks, suggesting potential functional applications.

Abstract

Three three-dimensional (3D) Tb(III) metal-organic frameworks (Tb-MOFs), {[Tb2(DMF)4(H2dobdc)4·DMF}n (Tb-MOF1), {[Tb2(DMA)2(H2O)2(H2dobdc)6·2DMA}n (Tb-MOF2), {[Tb2(DEF)6(H2dobdc)3}n (Tb-MOF3, H4dobdc = 2,5-di hydroxy-benzene-1,4-di-carboxylic acid; DMF = N, N-dimethylformamide, DEF = N, N-diethylformamide, and DMA = Dimethylacetamide),...

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Cite This Study

Huang et al. (2025) studied this question.

synapsesocial.com/papers/68e0450fa99c246f578b4065 https://doi.org/10.1039/d5ce00881f

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Controlling topological diversity and magnetic properties in three Tb(III) metal−organic frameworks through amide ligands variation

Key Points

Implication

Abstract

Discussion

Cite This Study

Controlling topological diversity and magnetic properties in three Tb(III) metal−organic frameworks through amide ligands variation

Key Points

Implication

Abstract

Discussion

Cite This Study

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