We provide a probabilistic proof of the fundamental gap estimate for Schrödinger operators in convex domains on the sphere, which extends the probabilistic proof of F. Gong, H. Li, and D. Luo [Potential Anal. 44 (2016), pp. 423–442] for the Euclidean case. Our results further generalize the results achieved for the Laplacian by S. Seto, L. Wang, and G. Wei [J. Differential Geom. 112 (2019), pp. 347–389], as well as by C. He, G. Wei, and Qi S. Zhang [Amer. J. Math. 142 (2020), pp. 1161–1191]. The essential ingredient in our analysis is the reflection coupling method on Riemannian manifolds.
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