Yield stress fluids solidifying in capillary imbibition

When subjected to external stress exceeding their yield stress ( σ Y ), yield stress fluids (YSFs) undergo transition from solid to liquid. While the flow dynamics of capillary flows – including wetting, coating, spreading, and wicking – can be predicted accurately for fluids without yield stress, only a few asymptotic solutions have been validated against experiments for YSFs. In this study, we explore experimentally and theoretically the entire dynamics and solidifying process during capillary imbibition of YSFs, representing the fundamental aspect of capillarity-driven flow. We observe that during the gradual deceleration of capillary rise, YSFs exhibit apparent flow below σ Y . This unexpected behaviour is linked to wall slip, manifested as plug flow in particle image velocimetry analyses. We introduce a model with numerical solutions, grounded in the rheological properties of YSFs and slip mechanisms, to accurately describe this liquid–solid transitional behaviour.