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September 27, 2024Organic Letters

Nucleophilic Ring Opening of Donor–Acceptor Cyclopropanes through Umpolung Reactivity of Organochlorophosphines: Phosphine Oxide-Functionalized Boron-Pendanted Compounds

Braj Gopal Manisha Lamba Apoorv Kushwaha Prasoon Raj Singh T. J. Dhilip Kumar Avijit Goswami

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Abstract

We present a novel set of frustrated Lewis pair (FLP) systems that exhibit a remarkable ability to promote the ring opening of donor-acceptor cyclopropanes (DACs). This FLP-promoted protocol offers umpolung reactivity of R

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Gopal et al. (2024) studied this question.

synapsesocial.com/papers/68e572d6b6db6435875137d4 https://doi.org/10.1021/acs.orglett.4c02418

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