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September 16, 2024The Journal of Organic Chemistry

Asymmetric Transfer Hydrogenation of gem-Difluorocyclopropenyl Ketones: The Synthesis and Functionalization of Enantioenriched cis gem-Difluorocyclopropyl Ketones

Olivier Charron Marharyta Kosiuha Phannarath Phansavath Virginie Ratovelomanana-Vidal Geoffrey Gontard Christophe Meyer

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The asymmetric transfer hydrogenation of

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Charron et al. (2024) studied this question.

synapsesocial.com/papers/68e58481b6db643587521b39 https://doi.org/10.1021/acs.joc.4c01497

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Synapse has enriched 5 closely related papers on similar clinical questions. Consider them for comparative context:

1Regio- and Diastereoselective Hydrophosphination and Hydroamidation of <i>gem</i>-Difluorocyclopropenes2024 · 7 citations
2Stereodivergent Palladium-Catalyzed C–F Bond Functionalization of <i>gem</i>-Difluoroalkenes2024 · 12 citations
3Efficient Access to Enantioenriched <i>gem</i>-Difluorinated Heterocycles via Silver-Catalyzed Asymmetric Cycloaddition Reaction2024 · 9 citations
4Enantioselective Synthesis α-Gem-Difluorinated Alcohols via Rh(III)-Catalyzed Transfer Hydrogenation2024
5Regioselective Difunctionalization of <i>gem</i> -Difluorocyclopropanes via Palladium-Catalyzed Defluorinative Coupling2025 · 3 citations

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Light-Induced PdH-Catalyzed Cross-Dimerization of <i>gem</i> -Difluoroalkenes with Alkenes to Access CF <sub>2</sub> H Motifs2026

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