Room temperature nanoimprint aided by electron beam irradiation for polysilsesquioxane

Recently, application of inorganic nano-periodic structure become an active area of research. Polysilsesquioxane (PSQ) is known as hydrolytically stable organic-inorganic hybrid material and this study propose a room temperature (RT) nanoimprint using methylated poly silsesquioxane (Me-PSQ) dissolved in high-boiling solvent. PSQ electron beam cross-linked by a high electron beam irradiation maintained the shape of nanopatterns and enhanced the heat resistance. As a result of analysis of fourier transform infrared spectrophotometer (FT-IR), a siloxane linkage (Si-O-Si bridging) constitutes a core element of PSQ. The peak wavenumber of Si-O-Si bridging at cross-linked PSQ by electron beam irradiationshifted from 1115 to 1135 cm-1. The peaks of shifted towards the high wavenumber side and approached the second peak (1170 cm-1) of the Si-O-Si stretching vibration of quartz. This result suggests that the physical properties of electron-beam irradiated PSQ approach those of quartz.