Physical and numerical simulation of heat and mass transfer in the furnace of a thermogravimetric analyzer

A numerical study of the processes of heat and mass transfer in the furnace of a thermogravimetric analyzer was carried out, aimed at improving the accuracy of determining the kinetic characteristics of samples during their thermal transformations in different media. Validation of the model and prognostic estimates were carried out in relation to specially conducted thermogravimetric studies of the conversion of fossil and renewable carbon-containing raw materials in successive processes of decarbonization (combustion) and carbonation (mineralization of ash residue). The application of the study results allows to calculate the actual concentrations of the reagent over the sample uncontrolled by the device during pulsed switching of media and the actual temperatures of the sample during its thermochemical transformations.