Groundwater–rock interactions and mixing in fault-controlled karstic aquifers: A structural, hydrogeochemical and multi-isotopic review of the Pontina Plain (Central Italy)

Karstic aquifers represent crucial water resources and are categorized as either stratigraphically or fault-controlled. This study investigates groundwater-rock interactions and mixing processes within one of the largest fault-controlled karstic aquifers in Central Italy, adjacent to the Pontina plain, which is a highly populated area where agricultural activities and climate change challenge the groundwater assessment of a complex aquifer. We conducted structural, hydrogeochemical, and multi-isotopic screening of ten selected springs with different degrees of mineralization (ranging from Ca-HCO