Electrochemical Conversion of Bicarbonate Using Proton Exchange Membrane-Based Electrolyzer

Direct electrochemical conversion of captured carbon dioxide (CO 2 ) is gaining interest as an efficient method for capturing and utilizing CO 2 , eliminating the need for energy-intensive CO 2 separation process. [1] The integrated electrolyzer with bicarbonate feed operates on the principle of spontaneous reduction of CO 2 released from bicarbonate within the electrolyzer. The key to the on-site decomposition of bicarbonate into CO 2 is to acidify the bicarbonate within the electrolyzer through the deliberately generated pH gradient. Bipolar membrane has been extensively used to generate pH gradient and acidify the bicarbonate feed. [2] However, the high ionic resistivity of bipolar membrane and slow kinetic of water dissociation reaction can result in a high operation cell voltage. In this study, we demonstrate proton exchange membrane based-bicarbonate electrolyzer which produces carbon monoxide from bicarbonate feedstock with high CO production selectivity and low cell voltage that are comparable to the conventional gas fed CO 2 electrolyzer. To achieve highly selective CO production selectivity, a nickel single atom catalyst (Ni SAC) where the atomically dispersed nickel active sites decorated on the nitrogen doped carbon was prepared and utilized. Ni-SAC showed high CO production selectivity even in bicarbonate feed electrolyzer. To further improve the performance of this integrated electrolyzer, significant attention was given to the optimization of electrode structures. Due to the complexity of the reaction environment within the integrated electrolzyer, the performance of the electrolyzer is heavily dependent on the porosity of electrodes and distribution of catalyst on the electrodes. By optimizing the fabrication of electrodes with Ni-SACs, the optimal catalyst coated electrode showed high CO production selectivity over 90% with current density of 100 mA/cm 2 at low operating cell potential of 3 V. References [1] M. C. Freyman, Z. Huang, D. Ravikumar, E. B. Duoss, Y. Li, S. E. Baker, S. H. Pang and J. A. Schaidle, Joule , 2023, 7 , 631-651. [2] T. Li, E. W. Lees, M. Goldman, D. A. Salvatore, D. M. Weekes and C. P. Berlinguette, Joule , 2019, 3 , 1487-1497.