(Invited) Thermo-Electrochemical Stability of Solid-State Batteries

Solid-state batteries (SSBs) are promising due to higher energy density and improved safety. While interface instability due to electrochemical-mechanics interaction, transport and morphological dynamics at solid-solid interfaces has been identified as a critical determinant of failure modes, the role of thermo-electrochemical effect is still elusive. A wide range of factors, such as, high reactivity of lithium, propensity for hotspot formation (e.g., at solid/solid point contacts), and cathode instability may affect thermo-electrochemical signature of solid-state architectures. In addition, spatio-temporal evolution of thermal and reaction heterogeneities and the occurrence of failure mechanisms such as lithium filament growth can be critical. In this presentation, the important role of internal thermal signature and mechanistic origin of thermo-electrochemical instability in solid-state battery architectures will be discussed.