High‐Capacity and Ultra‐Long‐Life Mg‐Metal Batteries Enabled by Intercalation‐Conversion Hybrid Cathode Materials

The advancement of rechargeable Mg‐metal batteries (RMBs) is severely impeded by the lack of suitable cathode materials. Despite the good cyclic stability of intercalation‐type compounds, their specific capacity is relatively low. Conversely, the conversion‐type cathodes can deliver a higher capacity but often suffer from poor cycling reversibility and stability. Herein, a WSe 2 /Se intercalation‐conversion hybrid material with elemental Se uniformly distributed into WSe 2 nanosheets is fabricated via a simple solvothermal method for high‐performance RMBs. The uniformly introduced Se confined in WSe 2 nanosheets can not only efficiently improve the conductivity of the hybrid cathodes, facilitating the fast electron transport and ion diffusion, but also provide additional specific capacity. Besides, the WSe 2 can effectively inhibit the detrimental Se dissolution and polyselenide shuttle, thereby activating the activity of Se and improving its utilization. Consequently, the synergy of intercalation and conversion mechanisms endows WSe 2 /Se hybrids with superior reversible capacity of 252 mAh g −1 at 0.1 A g −1 and ultra‐long cyclability of up to 5000 cycles at 2.0 A g −1 with capacity retention of 78.1%. This work demonstrates the feasibility of the strategy by integrating intercalation and conversion mechanisms for developing high‐performance cathode materials for RMBs.