A Flexible Electrochromic Device for All-Season Thermal Regulation on Curved Transparent Building Envelopes

As one of the least energy-efficient components in buildings, transparent building envelopes are responsible for approximately 60% of the total energy losses. Although controlling solar transmittance through electrochromic modulation is an effective method for temperature management in these structures, a dynamic control strategy for solar light on curved transparent building envelopes is still lacking. In this study, we introduce a dual-mode flexible electrochromic device based on reversible silver deposition for curved transparent building envelopes. The device operates by reversibly depositing and dissolving silver on a flexible polyethylene terephthalate-indium tin oxide (PET-ITO) substrate, controlled through the application and removal of pulsed voltage. This mechanism enables rapid switching between radiative cooling and solar heating modes, leading to modulation of solar reflectance from 89.1% to 15.7% and solar transmittance from 0.02% to 72.9%. Under approximately 700 W/m